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Names | |||
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IUPAC name
Disilane
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Identifiers | |||
3D model (JSmol)
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ChEBI | |||
ChemSpider | |||
ECHA InfoCard | 100.014.970 | ||
368 | |||
PubChem CID
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UNII | |||
CompTox Dashboard (EPA)
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Properties | |||
Si2H6 | |||
Molar mass | 62.218 g·mol−1 | ||
Appearance | Colourless gas | ||
Density | 2.7 g dm−3 | ||
Melting point | −132 °C (−206 °F; 141 K) | ||
Boiling point | −14 °C (7 °F; 259 K) | ||
Reacts[1] | |||
Vapor pressure | 2940.2±0.0 mmHg at 25°C[2] | ||
Conjugate acid | Disilanium | ||
Structure | |||
0 D | |||
Hazards | |||
Occupational safety and health (OHS/OSH): | |||
Main hazards
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Extremely flammable | ||
Related compounds | |||
Related disilanes
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Hexamethyldisilane | ||
Related compounds
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Disilane is a chemical compound with general chemical formula Si2R6 that was first identified in 1902 by Henri Moissan and Samuel Smiles (1877–1953) where R = H. Moissan and Smiles reported disilane as being among the products formed by the action of dilute acids on metal silicides. Although these reactions had been previously investigated by Friedrich Woehler and Heinrich Buff between 1857 and 1858, Moissan and Smiles were the first to explicitly identify disilane. They referred to disilane as silicoethane. Higher members of the homologous series SinH2n+2 formed in these reactions were subsequently identified by Carl Somiesky (sometimes spelled "Karl Somieski") and Alfred Stock.
At standard temperature and pressure, disilane is a colourless, acrid gas. Disilane and ethane have similar structures, although disilane is much more reactive. Other compounds of the general formula Si2X6 (X = hydrogen, halogen, alkyl, aryl, and mixtures of these groups) are called disilanes. Disilane is a group 14 hydride.