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Solid-state nuclear magnetic resonance

Solid-state 900 MHz (21.1 T[1]) NMR spectrometer at the Canadian National Ultrahigh-field NMR Facility for Solids

Solid-state nuclear magnetic resonance (ssNMR) is a spectroscopy technique used to characterize atomic-level structure and dynamics in solid materials. ssNMR spectra are broader due to nuclear spin interactions which can be categorized as dipolar coupling, chemical shielding, quadrupolar interactions, and j-coupling. These interactions directly affect the lines shapes of experimental ssNMR spectra which can be seen in powder and dipolar patterns. There are many essential solid-state techniques alongside advanced ssNMR techniques that may be applied to elucidate the fundamental aspects of solid materials. ssNMR is often combined with magic angle spinning (MAS) to remove anisotropic interactions and improve the sensitivity of the technique. The applications of ssNMR further extend to biology and medicine.

Bruker MAS rotors. From left to right: 1.3 mm (up to 67 kHz), 2.5 mm (up to 35 kHz), 3.2 mm (up to 24 kHz), 4 mm (up to 15 kHz), 7 mm (up to 7 kHz)
  1. ^ "National Ultrahigh-Field NMR Facility for Solids". Retrieved 2014-09-22.

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固体核磁気共鳴 Japanese Ressonância magnética nuclear de sólidos Portuguese 固态核磁共振波谱学 Chinese

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