Titanium oxide mineral
SEM BSE images showing kaitianite (Ktn) with tistarite (Tta), Ti,Al,Zr-oxide (TAZ), MgTi3+2Al4SiO12 phase (MTAS), spinel (Spl), sapphirine (Spr), and Ti-sulfide (Ti-S) in corundum Grain 1125C2. The upper rectangular area in (b) are enlarged in (c)[ 3]
Tistarite is an exceedingly rare mineral with the formula Ti2 O3 , thus being the natural analogue of titanium(III) oxide.[ 4] [ 2] In terms of chemistry it is the titanium -analogue of hematite , corundum , eskolaite , and karelianite . Other minerals with the general formula A2 O3 are arsenolite , avicennite , claudetite , bismite , bixbyite , kangite , sphaerobismoite , yttriaite-(Y) and valentinite . Tistarite and grossmanite – both found in the famous Allende meteorite (so is kangite) – are the only currently known minerals with trivalent titanium. Titanium in minerals is almost exclusively tetravalent.[ 2] [ 5] [ 6] The only known terrestrial occurrence of tistarite was found during minerals exploration by Shefa Yamim Ltd. in the upper mantle beneath Mount Carmel , Israel .[ 3] [ 7]
^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols" . Mineralogical Magazine . 85 (3): 291– 320. Bibcode :2021MinM...85..291W . doi :10.1180/mgm.2021.43 . S2CID 235729616 .
^ a b c Mindat, Tistarite, http://www.mindat.org/min-38695.html
^ a b W.L. Griffin; S.E.M. Gain; D.T. Adams; J-X. Huang; M. Saunders; V. Toledo; N.J. pearson; S.Y. O'Reilly (2016), "First terrestrial occurrence of tistarite (Ti2 O3 ): Ultra-low oxygen fugacity in the upper mantle beneath Mount Carmel, Israel" (PDF) , Geology , 44 (10), Geological Society of America (published 2016-08-17): 815– 818, Bibcode :2016Geo....44..815G , doi :10.1130/G37910.1 , archived (PDF) from the original on 2016-09-12, retrieved 2016-09-12 – via Shefa Yamim Ltd. This article incorporates text from this source, which is available under the CC BY 4.0 license.
^ Ma, C., and Rossmann, G.R., 2009: Tistarite, Ti2 O3 , a new refractory mineral from the Allende meteorite. American Mineralogist 94(5–6), 841–844
^ Mindat, Kangite, http://www.mindat.org/min-42879.html
^ Mindat, Yttriaite-(Y), http://www.mindat.org/min-40471.html
^ "Australian university confirms Israeli rare mineral discovery" . J-Wire . 2016-02-21. Archived from the original on 2016-02-22. Retrieved 2016-09-12 .