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Hydrogen halide

In chemistry, hydrogen halides (hydrohalic acids when in the aqueous phase) are diatomic, inorganic compounds that function as Arrhenius acids. The formula is HX where X is one of the halogens: fluorine, chlorine, bromine, iodine, astatine, or tennessine.[1] All known hydrogen halides are gases at standard temperature and pressure.[2]

Compound Chemical formula Bond length
d(H−X) / pm
(gas phase)
model Dipole
μ / D
Aqueous phase (acid) Aqueous Phase pKa values
hydrogen fluoride
(fluorane)
HF 1.86 hydrofluoric acid 3.1
hydrogen chloride
(chlorane)
HCl 1.11 hydrochloric acid -3.9
hydrogen bromide
(bromane)
HBr 0.788 hydrobromic acid -5.8
hydrogen iodide
(iodane)
HI 0.382 hydroiodic acid -10.4 [3]
hydrogen astatide
astatine hydride
(astatane)
HAt −0.06 hydroastatic acid ?
hydrogen tennesside
tennessine hydride
(tennessane)
HTs −0.24 ? hydrotennessic acid ? [4]
  1. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  2. ^ The Acidity of the Hydrogen Halides. (2020, August 21). Retrieved May 5, 2021, from https://chem.libretexts.org/@go/page/3699
  3. ^ Schmid, Roland; Miah, Arzu M. (2001). "The Strength of the Hydrohalic Acids". Journal of Chemical Education. 78 (1). American Chemical Society (ACS): 116. doi:10.1021/ed078p116. ISSN 0021-9584.
  4. ^ de Farias, Robson Fernandes (January 2017). "Estimation of some physical properties for tennessine and tennessine hydride (TsH)". Chemical Physics Letters. 667: 1–3. Bibcode:2017CPL...667....1D. doi:10.1016/j.cplett.2016.11.023.

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