Our website is made possible by displaying online advertisements to our visitors.
Please consider supporting us by disabling your ad blocker.

Responsive image


Peroxymonosulfuric acid

Peroxymonosulfuric acid
Skeletal formula of peroxymonosulfuric acid
Skeletal formula of peroxymonosulfuric acid
Ball and stick model of peroxymonosulfuric acid
Ball and stick model of peroxymonosulfuric acid
Names
IUPAC names
Peroxysulfuric acid
Sulfuroperoxoic acid[1]
Systematic IUPAC name
(Dioxidanido)hydroxidodioxidosulfur[1][2]
Other names
Peroxosulfuric acid[1]
Peroxomonosulfuric acid[citation needed]
Persulfuric acid[citation needed]
Caro's acid
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.028.879 Edit this at Wikidata
EC Number
  • 231-766-6
101039
UNII
UN number 1483
  • InChI=1S/H2O5S/c1-5-6(2,3)4/h1H,(H,2,3,4) checkY
    Key: FHHJDRFHHWUPDG-UHFFFAOYSA-N checkY
  • OOS(O)(=O)=O
  • [O].[O].OOSO
Properties
H
2
SO
5
Molar mass 114.078 g mol−1
Appearance White crystals
Density 2.239 g cm−3
Melting point 45 °C
Acidity (pKa) 1, 9.3[3]
Conjugate base Peroxomonosulfate
Structure
Tetrahedral at S
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
strong oxidizer
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Peroxymonosulfuric acid, also known as persulfuric acid, peroxysulfuric acid is the inorganic compound with the formula H2SO5. It is a white solid. It is a component of Caro's acid, which is a solution of peroxymonosulfuric acid in sulfuric acid containing small amounts of water.[4] Peroxymonosulfuric acid is a very strong oxidant (E0 = +2.51 V).

  1. ^ a b c International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry (IUPAC Recommendations 2005). Cambridge (UK): RSCIUPAC. ISBN 0-85404-438-8. p. 139. Electronic version.
  2. ^ "Peroxysulfuric acid (CHEBI:29286)". Chemical Entities of Biological Interest. UK: European Bioinformatics Institute. 20 November 2007. Retrieved 17 November 2011.
  3. ^ Perrin, D. D., ed. (1982) [1969]. Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution. IUPAC Chemical Data (2nd ed.). Oxford: Pergamon (published 1984). Entry 176. ISBN 0-08-029214-3. LCCN 82-16524.
  4. ^ Cite error: The named reference Ullmann was invoked but never defined (see the help page).

Previous Page Next Page