Nitrosonium

Nitrosonium
Names
	IUPAC name Nitrilooxonium
	Systematic IUPAC name Oxidonitrogen(1+)
	Other names Nitrosonium; Iminooxidanium
Identifiers
CAS Number	14452-93-8;
3D model (JSmol)	Interactive image;
Abbreviations	NO(+)
ChEBI	CHEBI:29120;
ChemSpider	76569;
Gmelin Reference	456
PubChem CID	84878;
CompTox Dashboard (EPA)	DTXSID901027026 DTXSID90932326, DTXSID901027026 ;
	InChI InChI=1S/NO/c1-2/q+1 Key: KEJOCWOXCDWNID-UHFFFAOYSA-N;
	SMILES N#[O+];
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

The nitrosonium ion is NO⁺, in which the nitrogen atom is bonded to an oxygen atom with a bond order of 3, and the overall diatomic species bears a positive charge. It can be viewed as nitric oxide with one electron removed. This ion is usually obtained as the following salts: NOClO₄, NOSO₄H (nitrosylsulfuric acid, more descriptively written ONSO₃OH) and NOBF₄. The ClO−4 and BF−4 salts are slightly soluble in acetonitrile CH₃CN. NOBF₄ can be purified by sublimation at 200–250 °C and 0.01 mmHg (1.3 Pa).^[2]

^ Nomenclature of Inorganic Chemistry : IUPAC Recommendations 2005 (Red Book). Cambridge: The Royal Society of Chemistry. 2005. p. 315. ISBN 978-0-85404-438-2.
^ Olah, George A.; Surya Prakash, G. K.; Wang, Qi; Li, Xing-ya; Surya Prakash, G. K.; Hu, Jinbo (15 October 2004). "Nitrosonium Tetrafluoroborate". Encyclopedia of Reagents for Organic Synthesis: rn058.pub2. doi:10.1002/047084289X.rn058.pub2. ISBN 0471936235.

[iupac2005-1] Nomenclature of Inorganic Chemistry : IUPAC Recommendations 2005 (Red Book). Cambridge: The Royal Society of Chemistry. 2005. p. 315. ISBN 978-0-85404-438-2.

[2] Olah, George A.; Surya Prakash, G. K.; Wang, Qi; Li, Xing-ya; Surya Prakash, G. K.; Hu, Jinbo (15 October 2004). "Nitrosonium Tetrafluoroborate". Encyclopedia of Reagents for Organic Synthesis: rn058.pub2. doi:10.1002/047084289X.rn058.pub2. ISBN 0471936235.

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