Trisilane

Trisilane
Stereo structural formula of trisilane with implicit hydrogens
Stereo structural formula of trisilane with implicit hydrogens
Ball and stick model of trisilane
Ball and stick model of trisilane
Names
IUPAC name
Trisilane
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.132.113 Edit this at Wikidata
EC Number
  • 616-514-9
UNII
UN number 3194
  • InChI=1S/H8Si3/c1-3-2/h3H2,1-2H3 checkY
    Key: VEDJZFSRVVQBIL-UHFFFAOYSA-N checkY
  • [SiH3] [SiH2] [SiH3]
Properties
H8Si3
Molar mass 92.319 g·mol−1
Appearance Colourless liquid
Odor Unpleasant
Density 0.743 g cm−3
Melting point −117 °C (−179 °F; 156 K)
Boiling point 53 °C (127 °F; 326 K)
Slowly decomposes[1]
Vapor pressure 12.7 kPa
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Pyrophoric
GHS labelling:
GHS02: FlammableGHS07: Exclamation mark
Danger
H250, H261, H315, H319, H335
P210, P222, P231+P232, P261, P264, P271, P280, P302+P334, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P402+P404, P403+P233, P405, P422, P501
Flash point < −40 °C (−40 °F; 233 K)
< 50 °C (122 °F; 323 K)
Related compounds
Related hydrosilicons
Disilane
Disilyne
Silane
Silylene
Related compounds
Propane
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Trisilane is the silane with the formula H2Si(SiH3)2. A liquid at standard temperature and pressure, it is a silicon analogue of propane. In contrast with propane, however, trisilane ignites spontaneously in air.[2]

  1. ^ Alfred Walter Stewart (1926). Recent Advances in Physical and Inorganic Chemistry. Longmans, Green and Company, Limited. p. 312. Retrieved 11 May 2021.
  2. ^ P. W. Schenk (1963). "Silanes". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 1. NY, NY: Academic Press. p. 680.

Trisilane

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