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Propynyllithium

Propynyllithium
Names
IUPAC name
1-Lithium-1-propyne
Other names
1-Propyn-1-yllithium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.022.604 Edit this at Wikidata
EC Number
  • 224-862-4
  • InChI=1S/C3H3.Li/c1-3-2;/h1H3;/q-1;+1
    Key: ATKCLEUSJFRRKA-UHFFFAOYSA-N
  • [Li+].CC#[C-]
Properties
C3H3Li
Molar mass 46.00 g·mol−1
Appearance Whitish powder
Decomposition
Hazards
GHS labelling:
GHS02: Flammable GHS05: Corrosive
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Propynyllithium is an organolithium compound with the chemical formula LiC
2
CH
3
. It is a white solid that is soluble in 1,2-dimethoxyethane, and tetrahydrofuran. To preclude its degradation by oxygen and water, propynyllithium and its solutions are handled under inert gas (argon or nitrogen).[1] Although commonly depicted as a monomer, propynyllithium adopts a more complicated cluster structure as seen for many other organolithium compounds.

  1. ^ Greeves, Nicholas (15 April 2001). "Propynyllithium". Encyclopedia of Reagents for Organic Synthesis. onlinelibrary.wiley.com. doi:10.1002/047084289X.rp277. ISBN 978-0471936237.

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Propinyllithium German Propynyllithium French Propynyllithium Dutch Propynyllithi VI 丙炔锂 Chinese

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